You can capture that heat with a high efficiency condensing furnace.
Furnace intake and exhaust.
However these combustion gases contain residual heat that is lost through the ventilation.
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Since high efficiency furnaces draw air directly from outside the furnace itself does not require a fresh air intake in order to replace inside air.
These types of furnaces have a dedicated pipeline that runs directly from an outside vent into a sealed combustion chamber of the furnace and a sealed vent to the outside of the home for venting the toxic fumes from the combustion process.
The exhaust pipe has two 90 degree fittings at the top of the pipe which gives a 180 degree turn and the exhaust opening is pointed straight down.
First locate your furnace and find the intake and exhaust pipes.
Once outside look for the intake and exhaust pipes.
At the top of the pvc pipe the intake has one 90 degree fitting so the opening is pointed straight out to the side of the vertical pipe.
Furnace intake and exhaust pvc.
My carrier furnace has two pvc pipes that go through the basement wall and up the side of the house.
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They are usually white or black pvc pipes that exit a wall near your furnace.
The exhaust system typically uses metal venting often routed into a chimney stack to exhaust the combustion gases created in the furnace fire chamber.